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The invention relates to a process for polymerizing a multi-modal polymer in the presence of a multilayer catalyst which comprises at least one metallocene compound of the formula (I)
which is characterized in that
a) a non-coordinating anion and optionally a co-non-coordinating counterion are bound to the cyclopentadienyl ring,
b) the transition metal compound is deposited on an organic support of the formula (II)
xe2x80x83wherein X is F, H or Cl and R1 to R4 are C1 to C20 alkyl groups or SiRbRcRdRe (C2 to C20 alkyl groups), which is characterized in that
c) the supported catalyst system is treated at least once in a solvent mixture comprising chlorinated hydrocarbons.
The invention relates in particular to a novel process for polymerizing a multi-modal polymer in the presence of a supported, multilayer catalyst system which comprises at least one metallocene compound of the formula I in which
a) a non-coordinating anion and optionally a co-non-coordinating counterion are bound to the cyclopentadienyl ring and
b) the transition metal compound is deposited on an organic support of the formula II.
In another embodiment of the invention, the supported catalyst system is treated, at least once, in a solvent mixture of chlorinated hydrocarbons.
Metallocene compounds of the formula I have been disclosed by U.S. Pat. No. 5,008,241, U.S. Pat. No. 4,937,299, U.S. Pat. No. 5,055,438, U.S. Pat. No. 5,057,475, U.S. Pat. No. 5,096,867 and U.S. Pat. No. 5,055,438.
An advantage of the supported catalyst system of the invention is that the catalyst is deposited on the support in a highly stable manner, which prevents the formation of cracks or

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